Bond Fixation in Annulenes. 8. Assessment of the Ring Inversion and Bond Shifting Barriers in 1,2,3-trimethylcyclooctatetraene. Resolution, Absolute Configuration and Circular Dichroism Behavior of an Annulene Hydrocarbon

DOI: 10.1021/ja00535a032

Source and publish data:

Journal of the American Chemical Society p. 5016 - 5025 (1980)

Update date:2022-09-26

Topics:

Authors:

Paquette, Leo A.

Gardlik, John M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00535a032

A synthesis of racemic 1,2,3-trimethylcyclooctatetraene (13) based upon the expectation that 1,7,8-trimethylbicyclo<4.2.0>octa-2,4,7-triene (12) would open disrotatorily under orbital symmetry control was realized.This <8>annulene demonstrated a ready pro

Full text of DOI:10.1021/ja00535a032

Products guided by the article

Product name:C₁₉H₁₉N₃O₂

Cas No:74438-04-3

R&D Labs maybe for 74438-04-3

Changzhou Anyi Biochem Co., Ltd.(expird)

Contact:+86-519-88836158

Address:no,51 caoda
Valiant Fine Chemicals Co., Ltd.

Contact:+86 535 6101878/6374484

Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
Shandong Yubin Chemical CO.,LTD

website:http://www.yukaichem.com/en.html

Contact:+86-536-8865336

Address:binhai economic development zone，262737 shangdong，china
HANGZHOU ICH BIOFARM CO.,LTD

Contact:+86-571-28186845

Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
NINGBO YINZHOU PRECISE COLOR CO.,LTD.

Contact:86-574-88139809 86-574-83033159

Address:Qiming Road,Yinzhou,Ningbo,China

Relevant to this article

Ratiometric fluorescent sensor based on inhibition of resonance for detection of cadmium in aqueous solution and living cells

Doi:10.1021/ic200032e
(2011)
Clavalanine (Ro 22-5417), a New Clavam Antibiotic from Streptomyces clavuligerus. 4. A Stereorational Synthesis

Doi:10.1021/jo00219a008
(1985)
Efficient lewis acid ionic liquid-catalyzed synthesis of the key intermediate of coenzyme Q10 under microwave irradiation

Doi:10.3390/molecules15129486
(2010)
Nonpeptide α_vβ₃ antagonists. Part 9: Improved pharmacokinetic profile through the use of an aliphatic, des-amide backbone

Doi:10.1016/j.bmcl.2004.06.068
(2004)
Methylaluminum bis(4-substituted-2,6-di-tert-butylphenoxide) as an efficient nonchelating Lewis acid: Application to asymmetric Diels-Alder reaction and diastereoselective alkylation to alkoxy carbonyl substrates

Doi:10.1016/S0040-4020(01)85366-7
(1994)
Synthesis of novel tetrahydropyran-based dipeptide isosters by overman rearrangement of 2,3-didehydroglycosides

Doi:10.1002/ejoc.200200710
(2003)

Article Doi