Bond Fixation in Annulenes. 8. Assessment of the Ring Inversion and Bond Shifting Barriers in 1,2,3-trimethylcyclooctatetraene. Resolution, Absolute Configuration and Circular Dichroism Behavior of an Annulene Hydrocarbon

DOI: 10.1021/ja00535a032

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Journal of the American Chemical Society p. 5016 - 5025 (1980)

Update date:2022-09-26

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Authors:

Paquette, Leo A.

Gardlik, John M.

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Article abstract of DOI:10.1021/ja00535a032

A synthesis of racemic 1,2,3-trimethylcyclooctatetraene (13) based upon the expectation that 1,7,8-trimethylbicyclo<4.2.0>octa-2,4,7-triene (12) would open disrotatorily under orbital symmetry control was realized.This <8>annulene demonstrated a ready pro

Full text of DOI:10.1021/ja00535a032

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