Tetrahedron p. 3129 - 3136 (1982)
Update date:2022-08-05
Topics:
Matthes, H.W.D.
Luu, B.
Ourisson, G.
Formic acid catalyzed rearrangement of zerumbone epoxide 3 gives three major bicyclic products, 4-6.The most important rearrangement is a conrotatory electrocyclic Nazarow reaction.The structures were deduced from spectral and chemical evidence. 13C NMR data are presented.An X-ray study has independently confirmed the proposed structures.
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