Silicon Phosphorus Analogies. Fluoride Activation of Nucleophilic Displacement at the Tetrahedral Phosphorus: An Example of Nucleophilic Assistance to Nucleophilic Substitution. 3

DOI: 10.1021/ja00316a041

Source and publish data:

Journal of the American Chemical Society p. 1060 - 1065 (1984)

Update date:2022-09-26

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Authors:

Corriu, Robert J. P.

Dutheil, Jean-Pierre

Lanneau, Gerard F.

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Article abstract of DOI:10.1021/ja00316a041

We report a mechanistic study of the activation of alcoholysis of the P-X bond (X= Cl, F) by F(1-).Cis and trans isomers of 2-halogeno-5-(chloromethyl)-5-methyl-2-oxo-1,3,2-dioxaphosphorinanes, 1 and 2, or their 2-thio analogues, 3 and 4, and epimeric 2-h

Full text of DOI:10.1021/ja00316a041

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