Silicon Phosphorus Analogies. Fluoride Activation of Nucleophilic Displacement at the Tetrahedral Phosphorus: An Example of Nucleophilic Assistance to Nucleophilic Substitution. 3

DOI: 10.1021/ja00316a041

Source and publish data:

Journal of the American Chemical Society p. 1060 - 1065 (1984)

Update date:2022-09-26

Topics:

Authors:

Corriu, Robert J. P.

Dutheil, Jean-Pierre

Lanneau, Gerard F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00316a041

We report a mechanistic study of the activation of alcoholysis of the P-X bond (X= Cl, F) by F(1-).Cis and trans isomers of 2-halogeno-5-(chloromethyl)-5-methyl-2-oxo-1,3,2-dioxaphosphorinanes, 1 and 2, or their 2-thio analogues, 3 and 4, and epimeric 2-h

Full text of DOI:10.1021/ja00316a041

Products guided by the article

Product name:5r-chloromethyl-2-fluoro-5-methyl-[1,3,2]dioxaphosphinane 2t-sulfide

Cas No:74737-13-6

R&D Labs maybe for 74737-13-6

Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI
UNION PHARMPRO CO.,LTD

Contact:18710867521(wechat)

Address:Rm10516,Galaxy Tech Building #2,No.25 Tangyan Rd,Hi-Tech Zone,Xi'an, China
Huzhou City Linghu Xinwang Chemical Co.,Ltd.

Contact:86-572-3948695/3945236

Address:huzhou
Jiangsu Institute of Ecomones Co., Ltd

website:http://www.jsmone.com

Contact:+86-519-82821700

Address:95 Huanyuan N. Road, Jintan, Jiangsu, China
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA

Relevant to this article

Diastereoselective synthesis of 10b-substituted hexahydropyrroloisoquinolines from L-tartaric acid. Creation of a quaternary carbon stereocentre via N-acyliminium ion cyclization

Doi:10.1016/j.tetlet.2004.06.036
(2004)
LEAVING GROUP DEPENDENT STEREOCHEMISTRY OF THIOALLENE FORMATION WITH PHENYLTHIOCOPPER PHOSPHINE COMPLEXES

Doi:10.1016/S0040-4039(00)94010-3
(1983)
Rate Constants for Halogen Atom Transfer from Representative α-Halocarbonyl Compounds to Primary Alkyl Radicals

Doi:10.1021/jo00269a016
(1989)
Doi:10.1021/ja00489a016
(1978)
Doi:10.1021/ja01567a046
(1957)
Non-covalent Interactions in Metal Complexes. II. Induction of Asymmetry in Cobalt(III) Complexes with Amino Acid-Schiff Bases. Importance of CH...?-Interaction in Determining Configuration of Complexes

Doi:10.1246/bcsj.53.2248
(1980)

Article Doi