Hydride Reduction of the Cation 5-C5H5)Fe(triphos)>PF6: Direct Nucleophilic Attack on the Metal, and Hydrogen Exchange in the Product Hydride (η5-C5H5)FeH(triphos) (triphos = Ph2PCH2CH2PPhCH2CH2PPh2)

DOI: 10.1039/c39800000159

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 159 - 160 (1980)

Update date:2022-08-03

Topics:

Authors:

Davies, Stephen G.

Felkin, Hugh

Watts, Oliver

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Article abstract of DOI:10.1039/c39800000159

Reduction of the cation <(η⁵-C5H5)Fe(triphos)>PF6 with lithium aluminium deuteride gives (η⁵-C5H5)FeD(triphos) which slowly undergoes H-D scrambling at 20 deg C (triphos = Ph2PCH2CH2PPhCH2CH2PPH2).

Full text of DOI:10.1039/c39800000159

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