Hydride Reduction of the Cation 5-C5H5)Fe(triphos)>PF6: Direct Nucleophilic Attack on the Metal, and Hydrogen Exchange in the Product Hydride (η5-C5H5)FeH(triphos) (triphos = Ph2PCH2CH2PPhCH2CH2PPh2)

DOI: 10.1039/c39800000159

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 159 - 160 (1980)

Update date:2022-08-03

Topics:

Authors:

Davies, Stephen G.

Felkin, Hugh

Watts, Oliver

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39800000159

Reduction of the cation <(η⁵-C5H5)Fe(triphos)>PF6 with lithium aluminium deuteride gives (η⁵-C5H5)FeD(triphos) which slowly undergoes H-D scrambling at 20 deg C (triphos = Ph2PCH2CH2PPhCH2CH2PPH2).

Full text of DOI:10.1039/c39800000159

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Fe(C₆H₅)2PCH₂CH₂P(C₆H₅)CH₂CH₂P(C₆H₅)2Cl₂]

Cas No:74890-14-5

R&D Labs maybe for 74890-14-5

TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Guangzhou PI & PI Biotech Inc. Ltd.

Contact:+86-20-81716320

Address:13th Floor, Xinbao Technology Industrial Park, No. 2 Ruixiang Road, Huangpu District, Guangzhou,Guangdong,China
Ningbo Distant Chemicals Co.,Ltd

Contact:86-574-27862490,27862438

Address:5F-3,#54 DaShaNi street,Ningbo,CHINA
Changsha Botaniex Inc.

Contact:(86) 731 88718666

Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
Jiaozuo Zhongwen Trading Coporation Limited

Contact:--

Address:East Renmin Road

Relevant to this article

Doi:10.1039/C39760000405
(1976)
Cycloaddition Reaction of Dimethyl Acetylenedicarboxylate with 2,4,5-Triphenyl-3H-pyrrol-3-one 1-Oxide

Doi:10.1021/jo01312a016
(1980)
Concise and protective group-free syntheses of (±)-hamigeran B and (±)-4-bromohamigeran B

Doi:10.1021/ol102780s
(2011)
1,3-Dialkylimidazolium-2-carboxylates as versatile N-heterocyclic carbene-CO₂ adducts employed in the synthesis of carboxylates and α-alkylidene cyclic carbonates

Doi:10.1016/j.tetlet.2008.10.107
(2009)
Microwave flash pyrolysis: C9h8 interconversions and dimerisations

Doi:10.1071/CH14238
(2014)
Insights into the binding of thiosemicarbazone derivatives with human serum albumin: Spectroscopy and molecular modelling studies

Doi:10.1080/07391102.2015.1075905
(2015)

Article Doi