Hydride Reduction of the Cation 5-C5H5)Fe(triphos)>PF6: Direct Nucleophilic Attack on the Metal, and Hydrogen Exchange in the Product Hydride (η5-C5H5)FeH(triphos) (triphos = Ph2PCH2CH2PPhCH2CH2PPh2)

DOI: 10.1039/c39800000159

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 159 - 160 (1980)

Update date:2022-08-03

Topics:

Authors:

Davies, Stephen G.

Felkin, Hugh

Watts, Oliver

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39800000159

Reduction of the cation <(η⁵-C5H5)Fe(triphos)>PF6 with lithium aluminium deuteride gives (η⁵-C5H5)FeD(triphos) which slowly undergoes H-D scrambling at 20 deg C (triphos = Ph2PCH2CH2PPhCH2CH2PPH2).

Full text of DOI:10.1039/c39800000159

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Fe(C₆H₅)2PCH₂CH₂P(C₆H₅)CH₂CH₂P(C₆H₅)2Cl₂]

Cas No:74890-14-5

R&D Labs maybe for 74890-14-5

Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Jiangsu Jiuri Chemical Co.,Ltd.

Contact:+86-519-82118868

Address:Tianwang Town, Jurong City, Jiangsu Province, China
Shandong Green Bio-Pharmaceutical Co.,Ltd

Contact:+86-530-5408622

Address:High-tech Development Zone, Heze City, Shandong, China
Shanghai Yanchu chemicals Co., Ltd

website:http://www.yanchuchem.com

Contact:0086 18601657701

Address:Room 1292, Building NO. 2, Lane 65, Huandong 1st Rd, Fengjing Town, Jinshan Distriction, shanghai
Wuxi Olite Chemical Co., Ltd.

Contact:86-510-82853889

Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China

Relevant to this article

Doi:10.1039/C39760000405
(1976)
Cycloaddition Reaction of Dimethyl Acetylenedicarboxylate with 2,4,5-Triphenyl-3H-pyrrol-3-one 1-Oxide

Doi:10.1021/jo01312a016
(1980)
Concise and protective group-free syntheses of (±)-hamigeran B and (±)-4-bromohamigeran B

Doi:10.1021/ol102780s
(2011)
1,3-Dialkylimidazolium-2-carboxylates as versatile N-heterocyclic carbene-CO₂ adducts employed in the synthesis of carboxylates and α-alkylidene cyclic carbonates

Doi:10.1016/j.tetlet.2008.10.107
(2009)
Microwave flash pyrolysis: C9h8 interconversions and dimerisations

Doi:10.1071/CH14238
(2014)
Insights into the binding of thiosemicarbazone derivatives with human serum albumin: Spectroscopy and molecular modelling studies

Doi:10.1080/07391102.2015.1075905
(2015)

Article Doi