Access to 3-Methyl-4-methylene-N-tosylpyrrolidine and 3,4-Dimethyl-N-tosylpyrroline by Ruthenium-Catalyzed Cascade Cycloisomerization/Isomerization Reactions

DOI: 10.1002/ejic.200300224

Source and publish data:

European Journal of Inorganic Chemistry p. 418 - 422 (2004)

Update date:2022-08-05

Topics:

Authors:

Oezdemir, Ismail

Cetinkaya, Engin

Cetinkaya, Bekir

Cicek, Metin

Semeril, David

Bruneau, Christian

Dixneuf, Pierre H.

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Article abstract of DOI:10.1002/ejic.200300224

New RuCl₂(benzimidazole)(arene) complexes have been prepared. Upon reaction with 1,1-diphenylprop-2-ynol they generate catalyst precursors which perform the cycloisomerization of diallyltosylamide into 3-methyl-4-methylene-N-tosylpyrrolidine. T

Full text of DOI:10.1002/ejic.200300224

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