Photolysis of the Dithiolactone 4-Isopropylidene-3,3-dimethyl-1-thiethan-2-thione; a Norrish Type I Reaction

DOI: 10.1039/c39800000243

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 243 - 244 (1980)

Update date:2022-08-05

Topics:

Authors:

Muthuramu, K.

Ramamurthy, V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39800000243

The dithiolactone (1) upon excitation gives the dithione (2) in cyclohexane and other aprotic solvents and a 1:1 adduct in hydroxylic solvents from an n?^* excited singlet state via an α-cleavage process.

Full text of DOI:10.1039/c39800000243

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1,2-Dithiolan-3-ol, 4,4-dimethyl-5-(1-methylethylidene)-, acetate

Cas No:75072-33-2

R&D Labs maybe for 75072-33-2

Shandong Wanda Organosilicon New Material Co., Ltd

Contact:+86-21-54177116;54302881

Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang
LianYunGang Chiral Chemical(CHINA) CO.,LTD

Contact:+86-518-83616958 +86-519-82884848

Address:LianYunGang Chemical Industry Park (JiangSu)
Nanjing Chemlin Chemical Co., Ltd.

website:http://www.echemlin.cn

Contact:+86-25-83697070

Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
ABA Chemicals (Shanghai) Limited

Contact:021- 5115 9199-232

Address:Suite 18D, #201 Ningxia Road,
lianyungang jinkang pharmaceutical technology co., ltd.

Contact:008651885445517

Address:Jinshan industrial park, Ganyu county, Lianyungang, Jiangsu Province, 222115, China

Relevant to this article

<4 + 2>-CYCLOADDITIONEN VON ENAMINOTHIONEN MIT MALEINSAEUREANHYDRID

Doi:10.1016/S0040-4039(01)81856-6
(1981)
QUATERNARY AMMONIUM SALTS WITH A LABILE <*>N-C BOND AS PRECURSORS OF MEDICINAL COMPOUNDS. II. COMPOUNDS WITH A LABILE <*>N-CH2+N GROUPING

Doi:10.1007/BF00758589
(1981)
Stereoselective construction of a 5-aza-spiro[2,4]heptane motif via catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides and ethyl cyclopropylidene acetate

Doi:10.1039/c0cc04329j
(2011)
A Quick and Clean Procedure for Synthesis of α-Aminophosphonates in Aqueous Media

Doi:10.1002/hc.21263
(2015)
Studies on cerebral protective agents. V. Novel 4-(3-nitrophenyl)pyridine and 4-(3-nitrophenyl)pyrimidine derivatives with anti-anoxic activity

Doi:10.1248/cpb.41.163
(1993)
Phenylacetylene dendrimers containing a fluorene core: Synthesis and spectroscopic studies

Doi:10.1002/cjoc.201090134
(2010)

Article Doi