Photolysis of the Dithiolactone 4-Isopropylidene-3,3-dimethyl-1-thiethan-2-thione; a Norrish Type I Reaction

DOI: 10.1039/c39800000243

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 243 - 244 (1980)

Update date:2022-08-05

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Authors:

Muthuramu, K.

Ramamurthy, V.

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Article abstract of DOI:10.1039/c39800000243

The dithiolactone (1) upon excitation gives the dithione (2) in cyclohexane and other aprotic solvents and a 1:1 adduct in hydroxylic solvents from an n?^* excited singlet state via an α-cleavage process.

Full text of DOI:10.1039/c39800000243

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