Tetrahedron Letters p. 1265 - 1268 (1980)
Update date:2022-08-05
Nishinaga, A.
Shimizu, T.
Matsuura, T.
The oxygenation of 4-(N-arylmethyleneamino)-2,6-di-t-butylphenols with Co(Salpr), a five coordinate Co(II) Schiff base complex, in CH2Cl2 results in the regioselective hydroperoxylation at the imino carbon to give N-(1-aryl-1-hydroperoxymethyl)-3,5-di-t-butyl-p-benzoquinone monoimines, which give exclusively the corresponding amides and 2,6-di-t-butyl-p-benzoquinone in an aerobic solution of KOH in 90percent EtOH.
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Doi:10.1039/P29800001331
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(2013)Doi:10.1080/10903120190939986
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(2020)Doi:10.1021/ja00391a022
(1981)
