Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1233 - 1237 (1990)
Update date:2022-08-05
Topics:
Moiseenkov, A. M.
Veselovskii, V. V.
Dragan, V. A.
Ignatenko, A. V.
Strelenko, Yu. A.
Low temperature electrophilic cyclization of α-geraniol, α-nerol, and α-linalool initiated by BF3*etherate leads to the formation of dimethylvinylcyclohexenes and bicyclo<3.2.1>octyl fluoride, which have monoterpene skeletons.The α-monoterpenol starting materials may be regarded as close models to labdadienols, and their transformation as mimicking the biosynthesis of diterpenes in the pimarane and gibbane series according to Wenkert.
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