ONE-STEP REGIOSPECIFIC SYNTHESIS OF ALLYLIC SILANES - EXTENSION TO BENZYLSILANES

DOI: 10.1016/S0040-4039(00)92798-9

Source and publish data:

Tetrahedron Letters p. 1857 - 1860 (1980)

Update date:2022-08-05

Topics:

Authors:

Lefort, Marcel

Simmonet, Christian

Birot, Marc

Deleris, Gerard

Dunogues, Jacques

Calas, Raymond

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Article abstract of DOI:10.1016/S0040-4039(00)92798-9

Allyltrichlorosilanes are prepared according to a one-step regiospecific process based on the reaction of allyl chlorides with SiCl4 and NiCp2/HMPA (catalyst), in the presence of industrial methylchlorodisilane fraction.Benzyltrihalosilanes are similarly obtained.

Full text of DOI:10.1016/S0040-4039(00)92798-9

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