Tetrahedron Letters p. 1857 - 1860 (1980)
Update date:2022-08-05
Topics:
Lefort, Marcel
Simmonet, Christian
Birot, Marc
Deleris, Gerard
Dunogues, Jacques
Calas, Raymond
Allyltrichlorosilanes are prepared according to a one-step regiospecific process based on the reaction of allyl chlorides with SiCl4 and NiCp2/HMPA (catalyst), in the presence of industrial methylchlorodisilane fraction.Benzyltrihalosilanes are similarly obtained.
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