Carbohydrate Research p. 75 - 86 (1982)
Update date:2022-07-30
Topics:
Buchanan, J. Grant
Edgar, Alan R.
Rawson, David I.
Shahidi, Parvin
Wightman, Richard H.
The (13)C-n.m.r. spectra of a range of isopropylidene acetals of carbohydrates have been studied.Attention has focused on the chemical shifts of the acetals carbon and methyl groups of the acetals.These parameters are characteristic of ring-size (1,3-dioxolane, and 1,3-dioxepane) and can sometimes give further information on ring-fusions and conformations.An example is given of the application of the method to 1,3:2,4:5,6-tri-O-isopropylidene-D-glucitol.
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