Lewis Acid Promoted Decomposition of Unsaturated α-Diazo Ketones. 2. A New Initiator for Polyolefinic Cationic Cyclization

DOI: 10.1021/ja00398a022

Source and publish data:

Journal of the American Chemical Society p. 2009 - 2016 (1981)

Update date:2022-07-30

Topics:

Authors:

Smith, Amos B.

Dieter, R. Karl

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00398a022

This report documents the first utilization of the unsaturated diazo ketone functionality in the initiation of polyolefinic cationic cyclizations.Specifically, β,γ-unsaturated diazo ketones 1 and 2 undergo a stereoselective Lewis acid promoted cyclization

Full text of DOI:10.1021/ja00398a022

Products guided by the article

Product name:cis-3a,9b-dimethyl-1,2,3a,4,5,9b-hexahydro-3H-benzinden-3-one

Cas No:76803-93-5

R&D Labs maybe for 76803-93-5

Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
ZHUHAI HAIRUIDE BIOSCIENCE AND TECHNOLOGY CO.,LTD

website:http://www.zhhairuide.com

Contact:+8613326687259/+86-756-7789199

Address:No.10 Yonghui Road
Beijing Pure Chem Co.,Ltd.

Contact:+86-10-83993285

Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China

Relevant to this article

NEW SYNTHETIC APPROACHES TO ASPIDOSPERMA ALKALOIDS WITH FUNCTIONALISED C(20) SUBSTITUENTS: SOME KEY INTERMEDIATES via DIENE-Fe(CO)3 COMPLEXES

Doi:10.1016/0040-4039(80)80222-X
(1980)
Tethered bis(amidate) and bis(ureate) supported zirconium precatalysts for the intramolecular hydroamination of aminoalkenes

Doi:10.1002/zaac.201400201
(2015)
Iminium ion catalysis: Use of the α-effect in the acceleration of the Diels-Alder reaction

Doi:10.1039/b212239a
(2003)
Artemisinin-dipeptidyl vinyl sulfone hybrid molecules: Design, synthesis and preliminary SAR for antiplasmodial activity and falcipain-2 inhibition

Doi:10.1016/j.bmcl.2009.04.100
(2009)
Carbon-Carbon Bond Formation by the Use of Chloroiodomethane as a C₁ Unit. III. A Convenient Synthesis of the Mannich Base from Enol Silyl Ether by a Combination of Chloroiodomethane and N,N,N',N'-Tetramethylmethanediamine

Doi:10.1246/bcsj.55.534
(1982)
Doi:10.1039/jr9500002855
(1950)

Article Doi