Lewis Acid Promoted Decomposition of Unsaturated α-Diazo Ketones. 2. A New Initiator for Polyolefinic Cationic Cyclization

DOI: 10.1021/ja00398a022

Source and publish data:

Journal of the American Chemical Society p. 2009 - 2016 (1981)

Update date:2022-07-30

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Authors:

Smith, Amos B.

Dieter, R. Karl

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Article abstract of DOI:10.1021/ja00398a022

This report documents the first utilization of the unsaturated diazo ketone functionality in the initiation of polyolefinic cationic cyclizations.Specifically, β,γ-unsaturated diazo ketones 1 and 2 undergo a stereoselective Lewis acid promoted cyclization

Full text of DOI:10.1021/ja00398a022

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