Novel Polysulphur Bridged Metacyclophanes from the Iron-catalysed Reaction of Bis-(2,4-dimethoxyphenyl) Sulphide with Disulphur Dichloride. Evidence for the Cleavage of the Carbon-Sulphur Bond by Electrophilic Agents

DOI: 10.1039/P19810000718

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 718 - 722 (1981)

Update date:2022-08-04

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Authors:

Bottino, Francesco

Pappalardo, Sebastiano

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Article abstract of DOI:10.1039/P19810000718

The iron-catalysed reaction of bis-(2,4-dimethoxyphenyl)sulphide (3) with disulphur dichloride (S2Cl2) in dilute chloroform solution has been investigated.Surprisingly, the reaction gives 4,6,11,13,18,20-hexamethoxy-1,2,9,16-tetrathia<2.1.1>metacyclophane

Full text of DOI:10.1039/P19810000718

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