Journal of the Chemical Society. Perkin transactions I p. 995 - 998 (1981)
Update date:2022-08-04
Topics:
Bernasconi, Silvana
Gariboldi, Pierluigi
Jommi, Giancarlo
Sisti, Massimo
Fava, Giovanni Gasparri
Sesquifilifolone (1), a cyclysation product of farnesic acid, has been reduced to the corresponding epimeric alcohols.These epimers (2) and (3) cyclise with rearrangement when treated with 50percent sulphuric acid to give a new sesquiterpene hydrocarbon C15H22, the structure of which has been determined by analysis of its spectroscopic properties, its reactivity, and by X-ray analysis of the rearranged monobromo-derivative 8-bromomethyl-1,4-dimethyl-9-methylenetetracyclo<5.2.1.15,8.04,10>undecane (8).
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(1994)
