Journal of the American Chemical Society p. 3252 - 3257 (1984)
Update date:2022-08-03
Topics:
Kitamura, Masato
Isobe, Minoru
Ichikawa, Yoshiyasu
Goto, Toshio
Chiral maytansinol (1) was synthesized stereoselectively from D-mannose.Asymmetric centers of 1 were induced intramolecularly from an asymmetric carbon corresponding to C-7 via the common key intermediate 3 for maytansinoids.Key points are (i) the usage o
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