Stereocontrolled Total Synthesis of (-)-Maytansinol

DOI: 10.1021/ja00323a032

Source and publish data:

Journal of the American Chemical Society p. 3252 - 3257 (1984)

Update date:2022-08-03

Topics:

Authors:

Kitamura, Masato

Isobe, Minoru

Ichikawa, Yoshiyasu

Goto, Toshio

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Article abstract of DOI:10.1021/ja00323a032

Chiral maytansinol (1) was synthesized stereoselectively from D-mannose.Asymmetric centers of 1 were induced intramolecularly from an asymmetric carbon corresponding to C-7 via the common key intermediate 3 for maytansinoids.Key points are (i) the usage o

Full text of DOI:10.1021/ja00323a032

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