Dipole Stabilization of α-Heteroatom Carbanions: Theory and Experiment

DOI: 10.1021/jo00333a049

Source and publish data:

Journal of Organic Chemistry p. 4108 - 4110 (1981)

Update date:2022-08-03

Topics:

Authors:

Rondan, Nelson G.

Houk, K. N.

Beak, Peter

Zajdel, William J.

Chandrasekhar, Jayaraman

Schleyer, Paul v. R.

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Article abstract of DOI:10.1021/jo00333a049

The results of ab initio SCF calculations verify dipole stabilization in the carbanions formed by loss of a proton from the methyl groups of methyl formate and N-methylformamide, but differences between theory for the free anions and experiment is attributed to the effect of lithium ion complexation.

Full text of DOI:10.1021/jo00333a049

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