VINYL MIGRATION IN THE OXYTHALLATION OF SOME 1,3-DIENES

DOI: 10.1246/cl.1981.997

Source and publish data:

Chemistry Letters p. 997 - 1000 (1981)

Update date:2022-08-05

Topics:

Authors:

Murakami, Masashi

Nishida, Shinya

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1981.997

The oxythallation of certain 1,3-dienes with thallium (III) nitrate trihydrate in MeOH-CH2Cl2 at 0-20 deg C gave products after vinyl migration .Methyl 1-methylcyclopropyl ketone, obtained in the reaction of 2,3-dimethyl-1,3-butadiene, was presumably derived from a cyclopropylmethyl cation, an intermediate in the vinyl migration.

Full text of DOI:10.1246/cl.1981.997

Products guided by the article

Product name:3-Dimethoxymethyl-cyclopentene

Cas No:79439-31-9

R&D Labs maybe for 79439-31-9

SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd

Contact:0086-10-64430626

Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
N&R INDUSTRIES,INC

Contact:Tel:+86-29-88764861 Fax:+86-29-88764861

Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China
Luojiang Chenming Biological Products Co

Contact:+86 15000297032

Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,
Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China

Relevant to this article

The total synthesis of (±)-trichostatin A. Some observations on the acylation and alkylation of silyl enol ethers, silyl dienol ethers and a silyl trienol ether

Doi:10.1016/S0040-4020(01)88581-1
(1983)
A Simple Photochemical Conversion of Perfluoroalkyl Hydrides to Perfluoroalkyl Bromides Using Interhalogen Compounds

Doi:10.1021/jo00170a054
(1983)
A SILYL-FUNCTIONALIZED ALKYL AZIDE, TRIMETHYLSILYLMETHYL AZIDE; SYNTHESIS AND CYCLOADDITION REACTION TO ACETYLENIC DIPOLAROPHILES

Doi:10.1246/cl.1983.1131
(1983)
Novel palladacycles containing [C(sp², ferrocene), N, O] ^- or [C(sp², ferrocene), N, O]^2- terdentate ligands

Doi:10.1021/om050881o
(2006)
INDUCTION OF STRESS METABOLITE FORMATION IN SUSPENSION CULTURES OF VIGNA ANGULARIS

Doi:10.1016/0031-9422(83)80235-0
(1983)
Coordination chemistry of the solvated Ag^I and Au^I ions in liquid and aqueous ammonia, trialkyl and triphenyl phosphite, and tri-n-butylphosphine solutions

Doi:10.1021/ic060175v
(2006)

Article Doi