PERFLUOROALKYLTIN(IV) HALIDES: A NOVEL PERFLUOROALKYLATING AGENT FOR CARBONYL COMPOUNDS

DOI: 10.1246/cl.1981.1337

Source and publish data:

Chemistry Letters p. 1337 - 1338 (1981)

Update date:2022-08-04

Topics:

Authors:

Kitazume, Tomoya

Ishikawa, Nobuo

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Article abstract of DOI:10.1246/cl.1981.1337

Perfluoroalkyltin(IV) halides (R_fSnX2I) were prepared in situ by the oxidative addition of perfluoroalkyl iodides to tin(II) halide in N,N-dimethylformamide.Aldehydes and ketones readily reacted with R_fSnCl2I giving perfluoroalkylcarbinols in the N,N-dimethylformamide-pyridine system.R_fSnF2I, however, did not undergo the reactions with these carbonyl compounds.

Full text of DOI:10.1246/cl.1981.1337

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