Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 2. Synthesis of (+)-exo-Brevicomin

DOI: 10.1021/jo00345a006

Source and publish data:

Journal of Organic Chemistry p. 932 - 935 (1982)

Update date:2022-08-04

Topics: Synthesis Synthetic Routes Pheromones D-Glucose

Authors:

Sherk, Alfred E.

Fraser-Reid, Bert

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Article abstract of DOI:10.1021/jo00345a006

The hydrated, acyclic form of (+)-exo-brevicomin indicates that the chirality of the molecule resides in a D-threo glycol segment such as that found at C3 and C4 of D-glucose.Accordingly, "acyclic transfer" of this portion of the sugar into a suitable pre

Full text of DOI:10.1021/jo00345a006

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