Intramolecular Oxidative Cyclization Reactions of Trivalent Phosphorus and Carbonyl Functions

DOI: 10.1021/ja00373a027

Source and publish data:

Journal of the American Chemical Society p. 2497 - 2501 (1982)

Update date:2022-08-03

Topics: Oxidation Cyclization Product Formation Nucleophilic Attack Carbonyl Compounds Trivalent Phosphorus Compounds Oxidants

Authors:

Harper, S. D.

Arguengo, Anthony J.

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Article abstract of DOI:10.1021/ja00373a027

Phosphonous diesters derived from the reaction of phenylphosphonous dichloride with 2-ketophenols readily undergo head-to-tail intramolecular cyclization in cases where the carbonyl function is an aldehyde, trifluoromethylacetophenone, or diaryl ketone.A

Full text of DOI:10.1021/ja00373a027

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