
Journal of Organic Chemistry p. 3319 - 3321 (1982)
Update date:2022-08-05
Topics:
Wilson, Stephen R.
Caldera, Patricia
Jester, Michael A.
The treatment of ketone thioketals with excess n-butyllithium in ether at 25 deg C leads to fragmentation to intermediate thioketones, which in most cases are further reduced to mercaptans via β-hydrogen transfer from n-butyllithium.Mercaptide anions form
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Doi:10.1021/ja00378a056
(1982)Doi:10.1248/cpb.32.2165
(1984)Doi:10.1021/ja00379a061
(1982)Doi:10.1016/S0040-4039(00)86910-5
(1982)Doi:10.1039/P29820000205
(1982)Doi:10.1021/jm0210562
(2003)