Tetrahedron p. 4305 - 4311 (1981)
Update date:2022-08-02
Topics:
Lewis, I. A. S.
MacLeod, J. K.
Oelrichs, P. B.
From chemical and spectroscopic evidence, the structure of the diterpenoid aglycone of wedeloside is proposed.The position of linkage of the previously described glycosidic moiety is established, allowing the structure of wedeloside to be formulated as (2β, 15α)-2-<<2-deoxy-2-(3-methyl-1-oxobutyl)amino-3-0-(1-oxo-3-phenylpropyl)-β-D-glucopyranosyl>oxy>-13,15-dihydroxykaur-16-ene-18,19-dioic acid.
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