STEREOISOMERS OF SELENILIMINES: ISOLATION AND REACTIONS OF 9-PHENYLSELENOXANTHENE-N-ARYLSULFONYLSELENILIMINES

DOI: 10.1016/S0040-4039(00)86978-6

Source and publish data:

Tetrahedron Letters p. 901 - 904 (1982)

Update date:2022-08-03

Topics:

Authors:

Hori, Mikio

Kataoka, Tadashi

Shimizu, Hiroshi

Tomimatsu, Kiminori

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Article abstract of DOI:10.1016/S0040-4039(00)86978-6

The isolated cis- and trans-9-phenylselenoxanthene-N-arylsulfonylselenilimines were not interconverted thermally. cis-Isomers were converted to trans-isomers by chloramine-T or -B in a fashion of S_N2 type substitution. cis-Isomers did not rearrange but trans-isomers rearranged thermally to 9-arylsulfonamido-9-phenylselenoxanthenes, whereas both isomers underwent the base-catalyzed intermolecular rearrangement.

Full text of DOI:10.1016/S0040-4039(00)86978-6

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