Chemical Communications p. 1765 - 1766 (1996)
Update date:2022-08-03
Topics:
Muir, Jayne E.
Haynes, Anthony
Winter, Mark J.
Treatment of the anionic carbene complex [W(=CHPh)(CO)2(η-C5H5)]- with MeI affords a complex trans-[WMe(=CHPh)(CO)2(η-C5H5)] which isomerises by means of an intramolecular methyl to carbene migration to afford the η3-benzyl complex [W(η3-CH(Me)C6H5)(CO) 2(η-C5H5)].
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