Journal of Coordination Chemistry p. 966 - 976 (2013)
Update date:2022-09-26
Topics: Syntheses X-ray structures Dioxomolybdenum(VI) complexes Catalytic oxidations
He, Xiao-Qiang
Two new dioxomolybdenum(VI) complexes, [MoO2L 1(CH30H)]CH30H (1) and [MoO2L 2(CH30H)] (2), where L1 and L2 are dianionic forms of N'-(3-bromo-2-hydroxybenzylidene)-4-hydroxybenzohydrazide and N'-(2-hydroxybenzylidene)-2-hydroxy-3-methylbenzohydrazide, respectively, have been synthesized. The complexes have been characterized by elemental analyzes, IR spectra, molar conductance data, and single crystal X-ray determination. Mo in each complex is octahedral. The crystals of the complexes are stabilized by hydrogen bonds and weak π π stacking interactions. The complexes function as effective olefin epoxidation catalysts with hydrogen peroxide as oxidant and sodium hydrogen carbonate as a co-catalyst at room temperature.
View MoreWuhan Hanye Chemical New Material Co.,Ltd
Contact:+86-27-85308141
Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD
website:http://www.fengrunhuagong.com
Contact:+86-536-7869976
Address:Changyi Coastal Economic Development Zone
Shanghai Sungo Technology Chemical Co., Ltd
Contact:0086-21-51385579
Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
Jiaxing Trustworthy Import And Export Co.,Ltd
Contact:+86-573-82030555
Address:Room 1202, Unit B, Charming plaza,No.1558 East Zhongshan Road , Jiaxing City, Zhejiang Province, China.
Anhui Gusheng Import&Export CO.,LTD
Contact:86-551-63662296
Address:Jinzhai Road NO.162 ,hefei, china
Doi:10.1080/00397911.2012.680569
(2013)Doi:10.1021/jo00152a039
(1983)Doi:10.1248/cpb.40.770
(1992)Doi:10.1021/ol047594l
(2005)Doi:10.1016/j.tetasy.2004.11.027
(2005)Doi:10.1007/BF00506618
(1982)