Tetrahedron Letters p. 3369 - 3372 (1982)
Update date:2022-08-04
Topics:
Bonin, Martine
Romero, Jose R.
Grierson, David S.
Husson, Henri-Philippe
The cis 2,6-dialkylpiperidine alkaloid (+/-) dihydro-pinidine 7b and the trans alkaloid (+/-) solenopsin A 5a were synthesized from a common α-aminonitrile synthon 1.The key step in this synthesis was the stereoselective reductive decyanation of the 1-benzyl-2-cyano-2',6-dialkylpiperidines 3a and 3b.
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Doi:10.1021/ja00343a037
(1983)Doi:10.1016/S0040-4039(00)88648-7
(1982)Doi:10.1007/s11176-005-0158-5
(2004)Doi:10.1055/s-1982-29921
(1982)Doi:10.1134/S1070363207120201
(2007)Doi:10.1002/anie.201811946
(2018)
