Bulletin of the Chemical Society of Japan p. 3671 - 3672 (1982)
Update date:2022-09-26
Topics:
Kikukawa, Kiyoshi
Kono, Kiyoshi
Wada, Fumio
Matsuda, Tsutomu
Reactions of arenediazonium tetrafluoroborates (ArN2BF4), acetonitrile and sodium carboxylates (RCOONa) gave N-acyl acetanilides (ArN(COR)COCH3) in moderate to good yields (Ar=Ph, 2-MeC6H4, 3-MeC6H4, 4-MeC6H4, 2,6-(Me)2C6H3; R=Et, i-Pr, t-Bu, Ph).Acrylonitrile and benzonitrile could be used in the reaction instead of acetonitrile.
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