Phosphorus, Sulfur and Silicon and the Related Elements p. 2617 - 2626 (2004)
Update date:2022-07-30
Topics:
Rixens, Berengere
Boutevin, Gilles
Boulahna, Ahmed
Hervaud, Yves
Boutevin, Bernard
Two phosphonated methacrylates containing urethane group were synthesized by reacting the isocyanatoethyl methacrylate (IEM; CH2=C(CH 3)COO(CH2)2NCO) and a phosphonated alcohol (OH(CH2)xP(O)(OMe)2, x = 1 or 2), and they are hydrolyzed into mono- and diacid monomers. All these products were characterized in 1H and 31P NMR. Unlike usual methods (esterification and transesterification), these syntheses were quantitative and easy to realize.
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