Enantioselective Synthesis of Seven Pyrrolizidine Diols from a Single Precursor

DOI: 10.1021/jo00223a002

Source and publish data:

Journal of Organic Chemistry p. 4425 - 4431 (1985)

Update date:2022-08-05

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Authors:

Chamberlin, A. Richard

Chung, John Y. L.

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Article abstract of DOI:10.1021/jo00223a002

The enantioselective synthesis of seven pyrrolizidine diols has been accomplished from a single, readily available intermediate.The key step of this general scheme involves an acetoxy-directed acyliminium ion-ketene dithioacetal cationic cyclization to gi

Full text of DOI:10.1021/jo00223a002

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