Reactions of K2[Fe(CO)3(PPh3)]: Reductive Sb-Sb coupling with Ph2SbCl to form trans-[Fe(CO) 3(PPh3)(Sb2Ph4)] and salt metathesis with Me3SbCl2 to yield trans-[Fe(CO)3(PPh 3)(SbMe3)]

DOI: 10.1002/ejic.200400683

Source and publish data:

European Journal of Inorganic Chemistry p. 82 - 85 (2005)

Update date:2022-08-05

Topics:

Authors:

Lorenz, Ingo-Peter

Rudolph, Stefan

Piotrowski, Holger

Polborn, Kurt

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Article abstract of DOI:10.1002/ejic.200400683

In contrast to the ferrate K₂[Fe(CO)₄], the phosphane-substituted ferrate K₂[Fe(CO)₃(PPh₃)] (1) reacts with the stibane derivative Ph₂SbCl by metal-assisted reductive Sb-Sb coupling to give the distibane complex trans-[Fe(CO) ₃(PPh₃)-(Sb₂Ph₄)] (3). The distibane ligand in 3 is terminally η¹-coordinated trans to the phosphane ligand. However, the stiborane derivative Me₃SbCl₂ reacts with 1 in a metathetical substitution reaction to form the monostibane complex trans-[Fe(CO)₃(PPh₃)(SbMe₃)] (5). Both compounds have been characterized by spectroscopic (IR, NMR, MS), analytical (C, H) and X-ray diffraction analyses. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.

Full text of DOI:10.1002/ejic.200400683

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