Total Synthesis of (-)-Colletol

DOI: 10.1021/jo00023a029

Source and publish data:

Journal of Organic Chemistry p. 6606 - 6611 (1991)

Update date:2022-07-30

Topics:

Authors:

Keck, Gary E.

Murry, Jerry A.

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Article abstract of DOI:10.1021/jo00023a029

The first total synthesis of the unsymmetrical bis-macrolide (-)-colletol is described.The synthesis involves a Lewis acid mediated addition of triphenylallylstannane to aldehyde 14 to set the C₁₂ stereochemistry.The penultimate step utilized m

Full text of DOI:10.1021/jo00023a029

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