Journal of Organic Chemistry p. 6606 - 6611 (1991)
Update date:2022-07-30
Topics:
Keck, Gary E.
Murry, Jerry A.
The first total synthesis of the unsymmetrical bis-macrolide (-)-colletol is described.The synthesis involves a Lewis acid mediated addition of triphenylallylstannane to aldehyde 14 to set the C12 stereochemistry.The penultimate step utilized m
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