Mechanistic Investigation of Reduction of Daunomycin and 7-Deoxydaunomycinone with Bi(3,5,5-trimethyl-2-oxomorpholin-3-yl)

DOI: 10.1021/ja00320a027

Source and publish data:

Journal of the American Chemical Society p. 2380 - 2387 (1984)

Update date:2022-08-04

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Authors:

Kleyer, Don L.

Koch, Tad H.

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Article abstract of DOI:10.1021/ja00320a027

The mechanisms of reduction of 7-deoxydaunomycinone (3) and daunomycin (1) by 3,5,5-trimethyl-2-oxomorpholin-3-yl (5), the one-electron reducing agent formed from bond homolysis of d,l-bi(3,5,5-trimethyl-2-oxomorpholin-3-yl) (4), are described.Reaction of

Full text of DOI:10.1021/ja00320a027

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