Tetrahedron p. 3737 - 3744 (1982)
Update date:2022-09-26
Topics:
Freeman, Peter K.
Swenson, Karl E.
Pyrolytic decomposition of the Li salt of the tosylhydrazone of 4,4-diphenyl-2,5-cyclohexadienone produces a mixture of biphenyl, o-terphenyl, p-terphenyl, methyl-o-terphenyl and the azine of 4,4-diphenyl-2,5-cyclohexadienone (13).Insight into the reaction pathway was provided by the pyrolytic decomposition of 2-deuterio tosylhydrazone 8a which generates o-terphenyl 10a and 10b in a ratio of 69:31.These results are interpreted in terms of the carbene rearrangements of Schemes 2, 3 and 5.
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Doi:10.1039/d0ob00546k
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