Trapping of Cyclopentadienone as a 4? Component in Diels-Alder Reactions with Ethyl Acrylate: a Simple Synthesis of (+/-)-Sarkomycin

DOI: 10.1039/c39840001049

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1049 - 1050 (1984)

Update date:2022-08-04

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Authors:

Baraldi, Pier Giovanni

Barco, Achille

Benetti, Simonetta

Pollini, Gian Piero

Polo, Eleonora

Simoni, Daniele

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Article abstract of DOI:10.1039/c39840001049

The ability of cyclopentadienone to act as the diene counterpart in Diels-Alder reactions was demonstrated through the isolation of the cycloadduct with ethyl acrylate, which was utilized as the starting point for an expeditious synthesis of (+/-)-sarkomycin.

Full text of DOI:10.1039/c39840001049

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