Journal of Organic Chemistry p. 4058 - 4067 (1983)
Update date:2022-08-04
Topics:
Mori, Miwako
Washioka, Yumiko
Urayama, Takao
Yoshiura, Kagari
Chiba, Katsumi
Ban, Yoshio
The insertion of carbon monoxide into vinyl halides bearing the secondary amine or alcohol with a catalytic amount of Pd(OAc)2 and PPh3 was realized to give five-, six-, and seven-membered lactams and lactones carrying α-methylene groups in fairly good yields.Bicyclic heterocycles, pyrrolizidine and indolizidine derivatives, were also synthesized from pyrrolidine and piperidine derivatives possessing vinyl halide groups in the side chain at the 2-position of the ring by means of palladium-catalyzed carbonylation.
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Doi:10.1002/hlca.19830660308
(1983)Doi:10.1021/om050507o
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(1980)