Journal of Organic Chemistry p. 3616 - 3618 (1983)
Update date:2022-08-02
Topics:
Burton, Donald J.
Naae, Douglas, G.
Flynn, Richard M.
Smart, Bruce E.
Brittelli, David R.
(Bromodifluoromethyl)triphenylphosphonium bromide undergoes facile exchange of the bromodifluoromethyl group with tertiary phosphine and trialkyl phosphite.A mechanism that involves formation of the difluoromethylene ylide and dissociation of the ylide into difluorocarbene and triphenylphosphine is proposed to account for the observed exchange process.
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