Journal of Organic Chemistry p. 3957 - 3960 (1983)
Update date:2022-07-30
Topics:
Bruneton, Jean
Shamma, Maurice
Minard, Robert D.
Freyer, Alan J.
Guinaudeau, Helene
The bark of Hernandia peltata Meissner (Hernandiaceae), gathered in the Republic of Vanuatu (New Hebrides), has yielded the bis(benzylisoquinolines) (+)-vanuatine (5), (+)-vateamine (6), and (+)-malekulatine (7).These are the first-known dimers of (+)-reticuline (2).Compounds 5 and 6 are products of tail-to-tail oxidative coupling, whereas 7 involves head-to-tail coupling.
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