Palladium-Catalyzed Polyhetero-Claisen Rearragement of 3-(Allylthio)-1,2,4-triazin-5(4H)-ones

DOI: 10.1021/jo00172a029

Source and publish data:

Journal of Organic Chemistry p. 4585 - 4589 (1983)

Update date:2022-08-05

Topics:

Authors:

Mizutani, Masato

Sanemitsu, Yuzuru

Tamaru, Yoshinao

Yoshida, Zen-ichi

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Article abstract of DOI:10.1021/jo00172a029

The S -> N allylic transposition of 3-(allylthio)-1,2,4-triazin-5(2H)-ones (2) has been performed successfully by catalysis of a palladium(II) salt, where regioselectivities of the rearrangement (N-2 vs.N-4) are highly dependent on the substitution patter

Full text of DOI:10.1021/jo00172a029

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