Substituents Effects. XVII. Rearrangement in the Acetolysis of 2-Arylethyl Tosylates

DOI: 10.1246/bcsj.60.1097

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1097 - 1102 (1987)

Update date:2022-08-05

Topics: Rearrangement Substituents Experimental Effects Tosylates Acetolysis XVII

Authors:

Fujio, Mizue

Goto, Mutsuo

Seki, Yoji

Mishima, Masaaki

Tsuno, Yuho

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.60.1097

The label scrambling within the ethylene chain of the final acetolysis products was determined for a series of α-D₂ labeled 2-arylethyl tosylates using proton NMR spectroscopy and the k_Δ/k_s values were derived from the scr

Full text of DOI:10.1246/bcsj.60.1097

Products guided by the article

Product name:1,1-Dideuterio-2-p-tolylethylalkohol

Cas No:87776-55-4

R&D Labs maybe for 87776-55-4

X.T.Y Environ-Tech Co.,Ltd

Contact:+86-310-7092106

Address:Quzhou Modern & New Industrial Park, Handan, Hebei 057250, China
Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang
Watson International Ltd

Contact:+44 (0)2036089360-31

Address:Chanceryhouse,Chancery Lan
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
shandong zhongke taidou chemical co.,ltd

Contact:86-531-88682301

Address:Jinan shandong Province CHina

Relevant to this article

A simple approach for the regioselective synthesis of imidazo[1,2-a] pyrimidiones and pyrimido[1,2-a]pyrimidinones

Doi:10.1016/j.tet.2005.11.014
(2006)
Design and synthesis of peripherally restricted transient receptor potential vanilloid 1 (TRPV1) antagonists

Doi:10.1021/jm7014638
(2008)
Retinoids and related compounds. Part 22. Synthesis of β-ionone analog tricarbonyliron complexes

Doi:10.1248/cpb.47.171
(1999)
Electronically Mismatched Cycloaddition Reactions via First-Row Transition Metal, Iron(III)-Polypyridyl Complex

Doi:10.1021/acs.orglett.8b02541
(2018)
Cyclization of the N-Butyl-5-methyl-1-hex-4-enaminyl Radical and the Use of N-Lithio-N-butyl-5-methyl-1-hex-4-enamine as a Mechanistic Probe for Electron-Transfer Processes

Doi:10.1021/ja00364a056
(1983)
Enantioselective organocatalytic michael/aldol sequence: Anticancer natural product (+)-trans-dihydrolycoricidine

Doi:10.1002/anie.201403065
(2014)

Article Doi