Tetrahedron Letters p. 5333 - 5336 (1983)
Update date:2022-08-04
Topics:
Mrozik
Chabala
Eskola
et al.
The structures of the avermectins and the milbemycins were interrelated by the conversion of 22,23-dihydroavermectin B(1a) and B(1b) aglycones into 13-deoxy-22,23-dihydroavermectin B(1a) aglycone and 13-deoxy-22,23-dihydroavermectin B(1b) aglycone corresponding to 26-ethyl milbemycin-α3 and milbemycin B-41D respectively via reduction of the protected 13-chloroaglycone derivatives.
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Doi:10.1021/jo00356a033
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