Synthesis of milbemycins from avermectins

DOI: 10.1016/S0040-4039(00)87861-2

Source and publish data:

Tetrahedron Letters p. 5333 - 5336 (1983)

Update date:2022-08-04

Topics:

Authors:

Mrozik Mrozik

Chabala Chabala

Eskola Eskola

et al. et al.

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Article abstract of DOI:10.1016/S0040-4039(00)87861-2

The structures of the avermectins and the milbemycins were interrelated by the conversion of 22,23-dihydroavermectin B(1a) and B(1b) aglycones into 13-deoxy-22,23-dihydroavermectin B(1a) aglycone and 13-deoxy-22,23-dihydroavermectin B(1b) aglycone corresponding to 26-ethyl milbemycin-α₃ and milbemycin B-41D respectively via reduction of the protected 13-chloroaglycone derivatives.

Full text of DOI:10.1016/S0040-4039(00)87861-2

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