Journal of Organic Chemistry p. 1371 - 1373 (1982)
Update date:2022-07-29
Topics:
Roush, William R.
Brown, Richard J.
Short, highly stereoselective syntheses of the title carbohydrates from allylic alcohol precursors are described.A synthesis of the racemic arabino-deoxyhexose is also described.These syntheses feature the highly regioselective epoxide ring opening reactions of intermediates 7, 11, and 12 and the asymmetric epoxidation-kinetic resolution of allylic alcohol 10.
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