Journal of the Chemical Society. Chemical communications p. 100 - 101 (1981)
Update date:2022-08-03
Topics:
Buss, Antony D.
Warren, Stuart
Pure Z-alkenes are obtained stereospecifically from erythro-alcohols (3) formed on addition of Ph2PO-stabilised anions to aldehydes; acylation of the same anions, reduction of the α-Ph2P(O) ketones (5) to the threo-alcohol (6), and elimination gives pure E-alkenes.
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