Chemistry Letters p. 881 - 882 (1998)
Update date:2022-08-04
Topics:
Fujio, Masakazu
Tanaka, Masakazu
Wu, Xiao-Ming
Funakoshi, Kazuhisa
Sakai, Kiyoshi
Suemune, Hiroshi
Asymmetric cyclization of 4-aryl-4-pentenals by using a cationic [Rh((R)-BINAP)]ClO4 afforded (3R)-3-substituted cyclopentanones; on the other hand, the cyclization of 4-pentenals bearing ortho-halogeno phenyl groups afforded the opposite (3S)-ones.
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