Asymmetric Catalysis of Ene-type Reaction with Fluoral by Chiral Titanium Complex: A Semi-empirical and Ab-initio Analysis of Ene Reactivity

DOI: 10.1016/S0040-4039(00)60408-2

Source and publish data:

Tetrahedron Letters p. 7591 - 7594 (1993)

Update date:2022-08-02

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Authors:

Mikami, Koichi

Yajima, Tomoko

Terada, Masahiro

Uchimaru, Tadafumi

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Article abstract of DOI:10.1016/S0040-4039(00)60408-2

The chiral titanium complex-catalyzed ene-type reaction with fluoral is shown to serve as an efficient route for the asymmetric synthesis of CF3-substituted compounds of biological and synthetic importance in extremely high enantiomeric excesses (>95perce

Full text of DOI:10.1016/S0040-4039(00)60408-2

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