An efficient synthesis of (+)-Anatoxin-a.

DOI: 10.1016/S0957-4166(00)82084-4

Source and publish data:

Tetrahedron Asymmetry p. 1263 - 1270 (1992)

Update date:2022-09-26

Topics:

Authors:

Skrinjar, Marco

Nilsson, Carita

Wistrand, Lars-G.

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Article abstract of DOI:10.1016/S0957-4166(00)82084-4

An efficient synthesis (38 percent overall yield in 8 steps starting from 2) of the potent neurotoxin (+)-anatoxin-a is described.The key step involves the stereoselective addition of 5-hexenylcopper to the chiral N-acyliminium ion 2a.

Full text of DOI:10.1016/S0957-4166(00)82084-4

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