Tetrahedron Asymmetry p. 1263 - 1270 (1992)
Update date:2022-09-26
Topics:
Skrinjar, Marco
Nilsson, Carita
Wistrand, Lars-G.
An efficient synthesis (38 percent overall yield in 8 steps starting from 2) of the potent neurotoxin (+)-anatoxin-a is described.The key step involves the stereoselective addition of 5-hexenylcopper to the chiral N-acyliminium ion 2a.
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