3,8-Bis(trimethylsiloxy)-6-bromo-6,7-dihydro-1-phenyl-1H-phosphonin 1-Oxide and Its Conversion to a Phosphonin Oxide and a Cyclopenta-λ5-phosphorin

DOI: 10.1021/jo00191a021

Source and publish data:

Journal of Organic Chemistry p. 3157 - 3161 (1984)

Update date:2022-08-05

Topics:

Authors:

Rao, Nandakumar S.

Quin, Louis D.

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Article abstract of DOI:10.1021/jo00191a021

Quantitative silylation of 5,6-dibromo-1-phenyl-3,8-phosphonanedione 1-oxide occurs with bis(trimethylsilyl)trifluoroacetamide, providing the 3,8-bis(trimethylsiloxy)derivative.Reaction of this water-sensitive compound with 1 equiv of triethylamine accomp

Full text of DOI:10.1021/jo00191a021

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