Radical cyclizations of bromo acylsilanes and intramolecular trapping of the rearranged α-silyloxy radicals

DOI: 10.1016/S0040-4039(00)91780-5

Source and publish data:

Tetrahedron Letters p. 1303 - 1306 (1993)

Update date:2022-08-03

Topics:

Authors:

Tsai, Yeun-Min

Tang, Kuo-Hsiang

Jiaang, Weir-Torn

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Article abstract of DOI:10.1016/S0040-4039(00)91780-5

Radical 1,5-exo cyclizations of acylsilanes involving secondary radicals are quite effective. In contrast 1,6-exo cyclizations are more sensitive toward steric effect. Tandem radical cyclization process can be designed.

Full text of DOI:10.1016/S0040-4039(00)91780-5

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