
Bulletin of the Chemical Society of Japan p. 1040 - 1045 (1984)
Update date:2022-08-02
Topics:
Harada
Shiono
Two isomers (E and Z) of benzoin oxime and 2-hydroxy-1-phenyl-1-propanone oxime were catalytically hydrogenated by using palladium on charcoal and erythro amino alcohols were obtained in about 80% diastereomeric excess. The syn-anti isomerization of these oximes in the presence of palladium on charcoal was also studied in connection with the stereoselectivity of the catalytic hydrogenation of the oximes.
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Doi:10.1002/ardp.19843170705
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