SYNTHESIS OF 2-ALKYLTHIO (OR TRIFLUOROMETHYLTHIO)-2-HALOGENOETHENYL DERIVATIVES BY MEANS OF WITTIG (UNDER PHASE TRANSFER CONDITIONS) OR WITTIG-HORNER REACTIONS. APPLICATION IN THE FIELD OF PYRETHROIDS.

DOI: 10.1016/S0040-4020(01)91800-9

Source and publish data:

Tetrahedron p. 1523 - 1532 (1984)

Update date:2022-08-03

Topics:

Authors:

Palla, Ottorino

Gozzo, Franco

Scaglioni, Leonardo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)91800-9

A mixture of RSCHCl₂, Ph₃P and trans-caronaldehyde ethyl ester, treated with aq.NaOH under phase transfer conditions, gave the corresponding 2-alkylthio, 2-chloroethenyl derivative, the product of the Wittig reaction of a phosphorane

Full text of DOI:10.1016/S0040-4020(01)91800-9

Products guided by the article

Product name:Cyclopropanecarboxylic acid, 2,2-dimethyl-3-[2-[(trifluoromethyl)thio]ethenyl]-, cyano(3-phenoxyphenyl)methyl ester

Cas No:91914-80-6

R&D Labs maybe for 91914-80-6

LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Chongqing Yawei Fine Chemical Co.,Ltd

Contact:0086-23-62849407

Address:Ziyou village, Nanquan town, Banan district, Chongqing China
New Forms

Contact:+31-24-3886056

Address:Binderskampweg 29 Unit 36
KA-SHING Business Trade Macau Co., Ltd.

Contact:00853-28430045

Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao
Shanghai Hongbang Medical Technology CO.,. Ltd

Contact:13671516988 /18917636693

Address:Room1, No67 Building, Yongde Road369, Wujing Town, Minhang Districy, Shanghai CIty, China.

Relevant to this article

Palladium-catalyzed direct arylation of benzoxazoles with unactivated simple arenes

Doi:10.1039/c2cc34238c
(2012)
Benzoquinazoline Inhibitors of Thymidylate Synthase: Methylenediamino-Linked Aroylglutamate Derivatives

Doi:10.1021/jm00032a019
(1994)
Convenient palladium-catalyzed aminocarbonylation of anilines to N-arylbenzamides

Doi:10.1016/j.tetlet.2011.04.111
(2011)
Palladium-catalyzed alkylation-alkenylation reactions: Rapid access to tricyclic mescaline analogues

Doi:10.1055/s-2006-941583
(2006)
N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates

Doi:10.1039/c7cc00891k
(2017)
Doi:10.1021/jo01063a030
(1961)

Article Doi