SYNTHESIS OF 2-ALKYLTHIO (OR TRIFLUOROMETHYLTHIO)-2-HALOGENOETHENYL DERIVATIVES BY MEANS OF WITTIG (UNDER PHASE TRANSFER CONDITIONS) OR WITTIG-HORNER REACTIONS. APPLICATION IN THE FIELD OF PYRETHROIDS.

DOI: 10.1016/S0040-4020(01)91800-9

Source and publish data:

Tetrahedron p. 1523 - 1532 (1984)

Update date:2022-08-03

Topics:

Authors:

Palla, Ottorino

Gozzo, Franco

Scaglioni, Leonardo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)91800-9

A mixture of RSCHCl₂, Ph₃P and trans-caronaldehyde ethyl ester, treated with aq.NaOH under phase transfer conditions, gave the corresponding 2-alkylthio, 2-chloroethenyl derivative, the product of the Wittig reaction of a phosphorane

Full text of DOI:10.1016/S0040-4020(01)91800-9

Products guided by the article

Product name:Cyclopropanecarboxylic acid, 2,2-dimethyl-3-[2-[(trifluoromethyl)thio]ethenyl]-, cyano(3-phenoxyphenyl)methyl ester

Cas No:91914-80-6

R&D Labs maybe for 91914-80-6

Engineering Research Center of Pesticide, Heilongjiang Province

Contact:+86-451-86609001

Address:No.74 of Xuefu Road, Nangang District,
HAORUI ENTERPRISES LLC

Contact:(1) 206-3550089

Address:5115 NE 8TH PL, Renton, WA 98059 USA
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
Hangzhou Haiqiang Chemical Co.,Ltd.

Contact:+86-571-86960370

Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province

Relevant to this article

Palladium-catalyzed direct arylation of benzoxazoles with unactivated simple arenes

Doi:10.1039/c2cc34238c
(2012)
Benzoquinazoline Inhibitors of Thymidylate Synthase: Methylenediamino-Linked Aroylglutamate Derivatives

Doi:10.1021/jm00032a019
(1994)
Convenient palladium-catalyzed aminocarbonylation of anilines to N-arylbenzamides

Doi:10.1016/j.tetlet.2011.04.111
(2011)
Palladium-catalyzed alkylation-alkenylation reactions: Rapid access to tricyclic mescaline analogues

Doi:10.1055/s-2006-941583
(2006)
N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates

Doi:10.1039/c7cc00891k
(2017)
Doi:10.1021/jo01063a030
(1961)

Article Doi