HIGHLY STEREOSELECTIVE C-ALLYLATION OF GLYCOPYRANOSIDES WITH ALLYLSILANES CATALYZED BY SILYL TRIFLATE OR IODOSILANE

DOI: 10.1016/S0040-4039(01)80261-6

Source and publish data:

Tetrahedron Letters p. 2383 - 2386 (1984)

Update date:2022-08-05

Topics:

Authors:

Hosomi, Akira

Sakata, Yasuyuki

Sakurai, Hideki

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Article abstract of DOI:10.1016/S0040-4039(01)80261-6

Methyl α-D-glucopyranoside, methyl α-D-mannopyranoside and, in particular, the corresponding α-D-glycopyranosyl chlorides readily undergo allylation with allylsilanes catalyzed by trimethylsilyl triflate or iodotrimethylsilane in a highly stereoselective mode.

Full text of DOI:10.1016/S0040-4039(01)80261-6

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