Platinum and palladium complexes of bicyclo[3.3.1]non-1-ene. Bonding and reactions of strained olefin-transition-metal complexes

DOI: 10.1021/om00121a016

Source and publish data:

Organometallics p. 296 - 302 (1985)

Update date:2022-08-03

Topics:

Authors:

Godleski, Stephen A.

Gundlach, Kurt B.

Valpey, Richard S.

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Article abstract of DOI:10.1021/om00121a016

Stable Pt(0) and Pt(II) complexes of bicyclo[3.3.1]non-1-ene have been prepared and exhibit considerable stability relative to the uncomplexed olefin. Despite NMR data indicating significant back-bonding in these complexes, unusually low barriers to rotat

Full text of DOI:10.1021/om00121a016

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